Absolutely, LiFe P04's point in the direction of getting us more range than anyone needs. And that's good. I'm certain to get some once I feel that I understand them well enough to justify the investment.
I do get the impression, though, that these are more prone to burst into flame if inadvertantly short-circuited. Though I'm willing to believe that this danger is small enough that their use is still justified. If they need to be treated with a little respect, then that's okay. I'm only quibbling with the word "safe" in case some total newbie is reading.
I have one question about them. And I promise I don't know the answer, nor do I think I know it.
Is there some ingredient in these batteries that is rare enough that truly widespread use will be impractical? Something that would make them too expensive or put a limit on how many can be built?
Perhaps I'm too skeptical there. But greater range at 1/3 of the weight is so nice. I'm wondering, though, if there's another shoe that hasn't dropped yet.
"LiFePo4 batteries are
"Lithium Iron Phosphate" batteries, and are relatively new on the scene. There is a really nice article on the Wikipedia website, which discusses the history and detail of the batteries.
http://en.wikipedia.org/wiki/Lithium_iron_phosphate_battery
The only challenge I have is with the inventor. I've always been told it was Quebec Hydro's invention, not a Texan. [I'll check out and get back.]
"Safety: LiFePO4 is an intrinsically safer cathode material than LiCoO2 and manganese spinel. The Fe-P-O bond is stronger than the Co-O bond, so that when abused, (short-circuited, overheated, etc.) the oxygen atoms are much harder to remove. This stabilization of the redox energies also helps fast ion migration. [citation needed]
As lithium migrates out of the cathode in a LiCoO2 cell, the CoO2 undergoes non-linear expansion that affects the structural integrity of the cell. The fully lithiated and unlithiated states of LiFePO4 are structurally similar which means that LiFePO4 cells are more structurally stable than LiCoO2 cells.[citation needed]
No lithium remains in the cathode of a fully charged LiFePO4 cell—in a LiCoO2 cell, approximately 50% remains in the cathode. LiFePO4 is highly resilient during oxygen loss, which typically results in an exothermic reaction in other lithium cells.[4]"
Have not personally heard of any challenge with safety from shorting, as I have from Nickel Cadium for example. As the 'Safe' rating I've seen is all 'Excellent' and none of our eConversion Members have mentioned or experience your issue, to my knowledge.
http://evie-systems.com/index.php?main_page=page&id=12
In addition,because the terminal connections on LiFePo4 Batteries are made of alluminum [weight reduction, among other things], instead of lead or copper, any acidental short would likely create an instant melting of the aluminum connection, avoiding the haszard you siscribe by acting as a fast blow fuse? [Just my guess] The multitude of small cells in series, that make up
e.g. 2.0+ klw storage in a 4 wheeler, is likely to restrict the effect to the cell or cells physically closest to any short, due ro rhe low indivivual cell voltage range:
"Cell voltage = min. discharge voltage = 2.8 V. Working voltage = 3.0 V – 3.3 V. Max. charge voltage = 3.6 V."
Oh yes:
The increased driving range comes from the major reduction in battery weight.
The increase in funtional temperature range, compared to lead acid, comes from the chemistry, as does the dramatic increase in battery life cycles.