that's just the way they're made, but you can port the exhaust and gasket match the port.
by the way, not all big block chevy engines had rectangular exhaust ports.
the high performance and marine heads have rectangular exhaust ports, and the truck, standard passenger big blocks had oval exhaust ports ports.
the oval port heads were more for low end torque, and the rectangular port heads were more for top end rpm's.
the rectaungular port heads flowed more than the oval port heads.