I doubt it will break, but the tubing might kink if you are not careful.
One messy but effective method is to completely fill up the exhaust with sand, packing it in tightly. Do NOT do this if you cannot take your muffler apart to clean out all of the sand though. Some mufflers are welded together, and if you cannot weld it back together after cutting the spot welds to get it open, you are screwed.
Another method is to heat up the tubing with a MAPP gas torch or Oxy-Acetylene torch and make a few shallow bends, being careful to not kink the tubing of course.
Some folks have just gotten lucky and clamped the pipe in a bench vice and bent the tubing by using a cheater pipe over the muffler.
There are many ways to get it done, just be careful. Do NOT kink the tubing.