I think you are overthinking this way too much. You've got a weak governed engine and you're further weakening its power output by going with 4 chains into an internal hub gear, so basically 5 ways for it to lose HP if (when) ONE of those goes out of alignment. Also, when you have the drive from the engine on one side and the output to the wheel on the other side, it puts a turning stress around the seat tube on all your components further stressing the drive shafts and reducing efficiency.
An ungoverned 79cc will rev out to around 6000rpm. There is a lot of small stuff you can do for now, like shaving the head .030" or more, advancing timing, opening up your intake and exhaust for example. THEN you can think about gearing-
Easy steps for any 4-stroker:
1. Set your gearing to top out just under max RPM at the speed you wanna go. IE 5500rpm @45mph ~ 9.4:1
2. Set your centrifugal clutch accordingly. You won't have good takeoff with the stock silver spring 2000rpm engagement, so put a black spring in there with either six heavy shoes or alternating heavy and regular shoes (AGK). Go to their website and buy the black spring and six heavy shoes. Don't even look at the green spring. Black spring with all heavy shoes = green spring with regular shoes. Mixing shoes will give you a full lockup around 3400rpm with an engagement of around 2500rpm, and all heavy will be around 3100 lockup and 2350 engagement. You won't even need to pedal to take off.
I know you might say oh well it's all setup and all... well believe me just try it. I went through all the stuff above, even made my own shift kit, setup a CVT, then went to single speed and now 2-speed. If you don't have any VERY steep hills around you then single is the way to go.
On my 2-speed I run a 8.15:1 top gear, 11.8:1 low gear, I have the black with all heavy in the primary and a yellow with all regular in the 2nd gear, it pulls hard in first gear then shifts at around 4800 rpm. After some more mods to the carburetor will be changing springs and shoes for even higher rpm shift to keep the engine in its power band (4000 - 5400)