You can't 'bore out' a 48cc cylinder and put a 66cc piston in it, there is no room.
The 66cc's have fatter and wider apart head bolts to accommodate the fatter cylinder and won't go on a 48cc bottom end either.
If you plan to re-use the 48, just do the basics first.
Pop the head and check inside for damage and debris, check the head gasket, then use an actual torque wrench and tighten the head to 12# ~4# at a time.